Experimental Researches in Electricity, Vol. 1 · Michael Faraday
§ 7. Identity of Electricities derived from different sources. § 8. Relation by measure of common and voltaic Electricity.
[Read January 10th and 17th, 1833.]
§ 7. Identity of Electricities derived from different sources.
265. The progress of the electrical researches which I have had the honour to present to the Royal Society, brought me to a point at which it was essential for the further prosecution of my inquiries that no doubt should remain of the identity or distinction of electricities excited by different means. It is perfectly true that Cavendish[A], Wollaston[B], Colladon[C], and others, have in succession removed some of the greatest objections to the acknowledgement of the identity of common, animal and voltaic electricity, and I believe that most philosophers consider these electricities as really the same. But on the other hand it is also true, that the accuracy of Wollaston's experiments has been denied[D]; and also that one of them, which really is no proper proof of chemical decomposition by common electricity (309. 327.), has been that selected by several experimenters as the test of chemical action (336. 346.). It is a fact, too, that many philosophers are still drawing distinctions between the electricities from different sources; or at least doubting whether their identity is proved. Sir Humphry Davy, for instance, in his paper on the Torpedo[E], thought it probable that animal electricity would be found of a peculiar kind; and referring to it, to common electricity, voltaic electricity and magnetism, has said, "Distinctions might be established in pursuing the various modifications or properties of electricity in those different forms, &c." Indeed I need only refer to the last volume of the Philosophical Transactions to show that the question is by no means considered as settled[F].
[A] Phil. Trans. 1779, p. 196.
[B] Ibid. 1801, p. 434.
[C] Annnles de Chimie, 1826, p. 62, &c.
[D] Phil. Trans. 1832, p. 282, note.
[E] Phil. Trans. 1892, p. 17.
"Common electricity is excited upon non-conductors, and is readily carried off by conductors and imperfect conductors. Voltaic electricity is excited upon combinations of perfect and imperfect conductors, and is only transmitted by perfect conductors or imperfect conductors of the best kind. Magnetism, if it be a form of electricity, belongs only to perfect conductors; and, in its modifications, to a peculiar class of them. Animal electricity resides only in the imperfect conductors forming the organs of living animals, &c."
Dr. Ritchie has shown this is not the case. Phil. Trans. 1832, p. 294.
[F] Phil. Trans. 1832, p. 259. Dr. Davy, in making experiments on the torpedo, obtains effects the same as those produced by common and voltaic electricity, and says that in its magnetic and chemical power it does not seem to be essentially peculiar,--p. 274; but he then says, p. 275, there are other points of difference; and after referring to them, adds, "How are these differences to be explained? Do they admit of explanation similar to that advanced by Mr. Cavendish in his theory of the torpedo; or may we suppose, according to the analogy of the solar ray, that the electrical power, whether excited by the common machine, or by the voltaic battery, or by the torpedo, is not a simple power, but a combination of powers, which may occur variously associated, and produce all the varieties of electricity with which we are acquainted?"
At p. 279 of the same volume of Transactions is Dr. Ritchie's paper, from which the following are extracts: "Common electricity is diffused over the surface of the metal;--voltaic electricity exists within the metal. Free electricity is conducted over the surface of the thinnest gold leaf as effectually as over a mass of metal having the same surface;--voltaic electricity requires thickness of metal for its conduction," p. 280: and again, "The supposed analogy between common and voltaic electricity, which was so eagerly traced after the invention of the pile, completely fails in this case, which was thought to afford the most striking resemblance." p. 291.
266. Notwithstanding, therefore, the general impression of the identity of electricities, it is evident that the proofs have not been sufficiently clear and distinct to obtain the assent of all those who were competent to consider the subject; and the question seemed to me very much in the condition of that which Sir H. Davy solved so beautifully,--namely, whether voltaic electricity in all cases merely eliminated, or did not in some actually produce, the acid and alkali found after its action upon water. The same necessity that urged him to decide the doubtful point, which interfered with the extension of his views, and destroyed the strictness of his reasoning, has obliged me to ascertain the identity or difference of common and voltaic electricity. I have satisfied myself that they are identical, and I hope the experiments which I have to offer and the proofs flowing from them, will be found worthy the attention of the Royal Society.
267. The various phenomena exhibited by electricity may, for the purposes of comparison, be arranged under two heads; namely, those connected with electricity of tension, and those belonging to electricity in motion. This distinction is taken at present not as philosophical, but merely as convenient. The effect of electricity of tension, at rest, is either attraction or repulsion at sensible distances. The effects of electricity in motion or electrical currents may be considered as 1st, Evolution of heat; 2nd, Magnetism; 3rd, Chemical decomposition; 4th, Physiological phenomena; 5th, Spark. It will be my object to compare electricities from different sources, and especially common and voltaic electricities, by their power of producing these effects.
I. Voltaic Electricity.
268. Tension.--When a voltaic battery of 100 pairs of plates has its extremities examined by the ordinary electrometer, it is well known that they are found positive and negative, the gold leaves at the same extremity repelling each other, the gold leaves at different extremities attracting each other, even when half an inch or more of air intervenes.
269. That ordinary electricity is discharged by points with facility through air; that it is readily transmitted through highly rarefied air; and also through heated air, as for instance a flame; is due to its high tension. I sought, therefore, for similar effects in the discharge of voltaic electricity, using as a test of the passage of the electricity either the galvanometer or chemical action produced by the arrangement hereafter to be described (312. 316.).
270. The voltaic battery I had at my disposal consisted of 140 pairs of plates four inches square, with double coppers. It was insulated throughout, and diverged a gold leaf electrometer about one third of an inch. On endeavouring to discharge this battery by delicate points very nicely arranged and approximated, either in the air or in an exhausted receiver, I could obtain no indications of a current, either by magnetic or chemical action. In this, however, was found no point of discordance between voltaic and common electricity; for when a Leyden battery (291.) was charged so as to deflect the gold leaf electrometer to the same degree, the points were found equally unable to discharge it with such effect as to produce either magnetic or chemical action. This was not because common electricity could not produce both these effects (307. 310.); but because when of such low intensity the quantity required to make the effects visible (being enormously great (371. 375.),) could not be transmitted in any reasonable time. In conjunction with the other proofs of identity hereafter to be given, these effects of points also prove identity instead of difference between voltaic and common electricity.
271. As heated air discharges common electricity with far greater facility than points, I hoped that voltaic electricity might in this way also be discharged. An apparatus was therefore constructed (Plate III. fig. 46.), in which AB is an insulated glass rod upon which two copper wires, C, D, are fixed firmly; to these wires are soldered two pieces of fine platina wire, the ends of which are brought very close to each other at e, but without touching; the copper wire C was connected with the positive pole of a voltaic battery, and the wire D with a decomposing apparatus (312. 316.), from which the communication was completed to the negative pole of the battery. In these experiments only two troughs, or twenty pairs of plates, were used.
272. Whilst in the state described, no decomposition took place at the point a, but when the side of a spirit-lamp flame was applied to the two platina extremities at e, so as to make them bright red-hot, decomposition occurred; iodine soon appeared at the point a, and the transference of electricity through the heated air was established. On raising the temperature of the points e by a blowpipe, the discharge was rendered still more free, and decomposition took place instantly. On removing the source of heat, the current immediately ceased. On putting the ends of the wires very close by the side of and parallel to each other, but not touching, the effects were perhaps more readily obtained than before. On using a larger voltaic battery (270.), they were also more freely obtained.
273. On removing the decomposing apparatus and interposing a galvanometer instead, heating the points e as the needle would swing one way, and removing the heat during the time of its return (302.), feeble deflections were soon obtained: thus also proving the current through heated air; but the instrument used was not so sensible under the circumstances as chemical action.
274. These effects, not hitherto known or expected under this form, are only cases of the discharge which takes place through air between the charcoal terminations of the poles of a powerful battery, when they are gradually separated after contact. Then the passage is through heated air exactly as with common electricity, and Sir H. Davy has recorded that with the original battery of the Royal Institution this discharge passed through a space of at least four inches[A]. In the exhausted receiver the electricity would strike through nearly half an inch of space, and the combined effects of rarefaction and heat were such upon the inclosed air us to enable it to conduct the electricity through a space of six or seven inches.
[A] Elements of Chemical Philosophy, p. 153
275. The instantaneous charge of a Leyden battery by the poles of a voltaic apparatus is another proof of the tension, and also the quantity, of electricity evolved by the latter. Sir H. Davy says[A], "When the two conductors from the ends of the combination were connected with a Leyden battery, one with the internal, the other with the external coating, the battery instantly became charged; and on removing the wires and making the proper connexions, either a shock or a spark could be perceived: and the least possible time of contact was sufficient to renew the charge to its full intensity."
[A] Elements of Chemical Philosophy, p. 154.
276. In motion: i. Evolution of Heat.--The evolution of heat in wires and fluids by the voltaic current is matter of general notoriety.
277. ii. Magnetism.--No fact is better known to philosophers than the power of the voltaic current to deflect the magnetic needle, and to make magnets according to certain laws; and no effect can be more distinctive of an electrical current.
278. iii. Chemical decomposition.--The chemical powers of the voltaic current, and their subjection to certain laws, are also perfectly well known.
279. iv. Physiological effects.--The power of the voltaic current, when strong, to shock and convulse the whole animal system, and when weak to affect the tongue and the eyes, is very characteristic.
280. v. Spark.--The brilliant star of light produced by the discharge of a voltaic battery is known to all as the most beautiful light that man can produce by art.
281. That these effects may be almost infinitely varied, some being exalted whilst others are diminished, is universally acknowledged; and yet without any doubt of the identity of character of the voltaic currents thus made to differ in their effect. The beautiful explication of these variations afforded by Cavendish's theory of quantity and intensity requires no support at present, as it is not supposed to be doubted.
282. In consequence of the comparisons that will hereafter arise between wires carrying voltaic and ordinary electricities, and also because of certain views of the condition of a wire or any other conducting substance connecting the poles of a voltaic apparatus, it will be necessary to give some definite expression of what is called the voltaic current, in contradistinction to any supposed peculiar state of arrangement, not progressive, which the wire or the electricity within it may be supposed to assume. If two voltaic troughs PN, P'N', fig. 42, be symmetrically arranged and insulated, and the ends NP' connected by a wire, over which a magnetic needle is suspended, the wire will exert no effect over the needle; but immediately that the ends PN' are connected by another wire, the needle will be deflected, and will remain so as long as the circuit is complete. Now if the troughs merely act by causing a peculiar arrangement in the wire either of its particles or its electricity, that arrangement constituting its electrical and magnetic state, then the wire NP' should be in a similar state of arrangement before P and N' were connected, to what it is afterwards, and should have deflected the needle, although less powerfully, perhaps to one half the extent which would result when the communication is complete throughout. But if the magnetic effects depend upon a current, then it is evident why they could not be produced in any degree before the circuit was complete; because prior to that no current could exist.
283. By current, I mean anything progressive, whether it be a fluid of electricity, or two fluids moving in opposite directions, or merely vibrations, or, speaking still more generally, progressive forces. By arrangement, I understand a local adjustment of particles, or fluids, or forces, not progressive. Many other reasons might be urged in support of the view of a current rather than an arrangement, but I am anxious to avoid stating unnecessarily what will occur to others at the moment.
II. Ordinary Electricity.
284. By ordinary electricity I understand that which can be obtained from the common machine, or from the atmosphere, or by pressure, or cleavage of crystals, or by a multitude of other operations; its distinctive character being that of great intensity, and the exertion of attractive and repulsive powers, not merely at sensible but at considerable distances.
285. Tension. The attractions and repulsions at sensible distances, caused by ordinary electricity, are well known to be so powerful in certain cases, as to surpass, almost infinitely, the similar phenomena produced by electricity, otherwise excited. But still those attractions and repulsions are exactly of the same nature as those already referred to under the head Tension, Voltaic electricity (268.); and the difference in degree between them is not greater than often occurs between cases of ordinary electricity only. I think it will be unnecessary to enter minutely into the proofs of the identity of this character in the two instances. They are abundant; are generally admitted as good; and lie upon the surface of the subject: and whenever in other parts of the comparison I am about to draw, a similar case occurs, I shall content myself with a mere announcement of the similarity, enlarging only upon those parts where the great question of distinction or identity still exists.
286. The discharge of common electricity through heated air is a well-known fact. The parallel case of voltaic electricity has already been described (272, &c.).
287. In motion. i. Evolution of heat.--The heating power of common electricity, when passed through wires or other substances, is perfectly well known. The accordance between it and voltaic electricity is in this respect complete. Mr. Harris has constructed and described[A] a very beautiful and sensible instrument on this principle, in which the heat produced in a wire by the discharge of a small portion of common electricity is readily shown, and to which I shall have occasion to refer for experimental proof in a future part of this paper (344.).
[A] Philosophical Transactions, 1827, p. 18. Edinburgh Transactions, 1831. Harris on a New Electrometer, &c. &c.
288. ii. Magnetism.--Voltaic electricity has most extraordinary and exalted magnetic powers. If common electricity be identical with it, it ought to have the same powers. In rendering needles or bars magnetic, it is found to agree with voltaic electricity, and the direction of the magnetism, in both cases, is the same; but in deflecting the magnetic needle, common electricity has been found deficient, so that sometimes its power has been denied altogether, and at other times distinctions have been hypothetically assumed for the purpose of avoiding the difficulty[A].
[A] Demonferrand's Manuel d'Electricité dynamique, p. 121.
289. M. Colladon, of Geneva, considered that the difference might be due to the use of insufficient quantities of common electricity in all the experiments before made on this head; and in a memoir read to the Academie des Sciences in 1826[A], describes experiments, in which, by the use of a battery, points, and a delicate galvanometer, he succeeded in obtaining deflections, and thus establishing identity in that respect. MM. Arago, Ampère, and Savary, are mentioned in the paper as having witnessed a successful repetition of the experiments. But as no other one has come forward in confirmation, MM. Arago, Ampère, and Savary, not having themselves published (that I am aware of) their admission of the results, and as some have not been able to obtain them, M. Colladon's conclusions have been occasionally doubted or denied; and an important point with me was to establish their accuracy, or remove them entirely from the body of received experimental research. I am happy to say that my results fully confirm those by M. Colladon, and I should have had no occasion to describe them, but that they are essential as proofs of the accuracy of the final and general conclusions I am enabled to draw respecting the magnetic and chemical action of electricity (360. 366. 367. 377. &c.).
[A] Annales de Chimie, xxxiii. p. 62.
290. The plate electrical machine I have used is fifty inches in diameter; it has two sets of rubbers; its prime conductor consists of two brass cylinders connected by a third, the whole length being twelve feet, and the surface in contact with air about 1422 square inches. When in good excitation, one revolution of the plate will give ten or twelve sparks from the conductors, each an inch in length. Sparks or flashes from ten to fourteen inches in length may easily be drawn from the conductors. Each turn of the machine, when worked moderately, occupies about 4/5ths of a second.
291. The electric battery consisted of fifteen equal jars. They are coated eight inches upwards from the bottom, and are twenty-three inches in circumference, so that each contains one hundred and eighty-four square inches of glass, coated on both sides; this is independent of the bottoms, which are of thicker glass, and contain each about fifty square inches.
292. A good discharging train was arranged by connecting metallically a sufficiently thick wire with the metallic gas pipes of the house, with the metallic gas pipes belonging to the public gas works of London; and also with the metallic water pipes of London. It was so effectual in its office as to carry off instantaneously electricity of the feeblest tension, even that of a single voltaic trough, and was essential to many of the experiments.
293. The galvanometer was one or the other of those formerly described (87. 205.), but the glass jar covering it and supporting the needle was coated inside and outside with tinfoil, and the upper part (left uncoated, that the motions of the needle might be examined,) was covered with a frame of wire-work, having numerous sharp points projecting from it. When this frame and the two coatings were connected with the discharging train (292.), an insulated point or ball, connected with the machine when most active, might be brought within an inch of any part of the galvanometer, yet without affecting the needle within by ordinary electrical attraction or repulsion.
294. In connexion with these precautions, it may be necessary to state that the needle of the galvanometer is very liable to have its magnetic power deranged, diminished, or even inverted by the passage of a shock through the instrument. If the needle be at all oblique, in the wrong direction, to the coils of the galvanometer when the shock passes, effects of this kind are sure to happen.
295. It was to the retarding power of bad conductors, with the intention of diminishing its intensity without altering its quantity, that I first looked with the hope of being able to make common electricity assume more of the characters and power of voltaic electricity, than it is usually supposed to have.
296, The coating and armour of the galvanometer were first connected with the discharging train (292.); the end B (87.) of the galvanometer wire was connected with the outside coating of the battery, and then both these with the discharging train; the end A of the galvanometer wire was connected with a discharging rod by a wet thread four feet long; and finally, when the battery (291.) had been positively charged by about forty turns of the machine, it was discharged by the rod and the thread through the galvanometer. The needle immediately moved.
297. During the time that the needle completed its vibration in the first direction and returned, the machine was worked, and the battery recharged; and when the needle in vibrating resumed its first direction, the discharge was again made through the galvanometer. By repeating this action a few times, the vibrations soon extended to above 40° on each side of the line of rest.
298. This effect could be obtained at pleasure. Nor was it varied, apparently, either in direction or degree, by using a short thick string, or even four short thick strings in place of the long fine thread. With a more delicate galvanometer, an excellent swing of the needle could be obtained by one discharge of the battery.
299. On reversing the galvanometer communications so as to pass the discharge through from B to A, the needle was equally well deflected, but in the opposite direction.
300. The deflections were in the same direction as if a voltaic current had been passed through the galvanometer, i.e. the positively charged surface of the electric battery coincided with the positive end of the voltaic apparatus (268.) and the negative surface of the former with the negative end of the latter.
301. The battery was then thrown out of use, and the communications so arranged that the current could be passed from the prime conductor, by the discharging rod held against it, through the wet string, through the galvanometer coil, and into the discharging train (292), by which it was finally dispersed. This current could be stopped at any moment, by removing the discharging rod, and either stopping the machine or connecting the prime conductor by another rod with the discharging train; and could be as instantly renewed. The needle was so adjusted, that whilst vibrating in moderate and small arcs, it required time equal to twenty-five beats of a watch to pass in one direction through the arc, and of course an equal time to pass in the other direction.
302. Thus arranged, and the needle being stationary, the current, direct from the machine, was sent through the galvanometer for twenty-five beats, then interrupted for other twenty-five beats, renewed for twenty-five beats more, again interrupted for an equal time, and so on continually. The needle soon began to vibrate visibly, and after several alternations of this kind, the vibration increased to 40° or more.
303. On changing the direction of the current through the galvanometer, the direction of the deflection of the needle was also changed. In all cases the motion of the needle was in direction the same as that caused either by the use of the electric battery or a voltaic trough (300).
304. I now rejected the wet string, and substituted a copper wire, so that the electricity of the machine passed at once into wires communicating directly with the discharging train, the galvanometer coil being one of the wires used for the discharge. The effects were exactly those obtained above (302).
305. Instead of passing the electricity through the system, by bringing the discharging rod at the end of it into contact with the conductor, four points were fixed on to the rod; when the current was to pass, they were held about twelve inches from the conductor, and when it was not to pass, they were turned away. Then operating as before (302.), except with this variation, the needle was soon powerfully deflected, and in perfect consistency with the former results. Points afforded the means by which Colladon, in all cases, made his discharges.
306. Finally, I passed the electricity first through an exhausted receiver, so as to make it there resemble the aurora borealis, and then through the galvanometer to the earth; and it was found still effective in deflecting the needle, and apparently with the same force as before.
307. From all these experiments, it appears that a current of common electricity, whether transmitted through water or metal, or rarefied air, or by means of points in common air, is still able to deflect the needle; the only requisite being, apparently, to allow time for its action: that it is, in fact, just as magnetic in every respect as a voltaic current, and that in this character therefore no distinction exists.
308. Imperfect conductors, as water, brine, acids, &c. &c. will be found far more convenient for exhibiting these effects than other modes of discharge, as by points or balls; for the former convert at once the charge of a powerful battery into a feeble spark discharge, or rather continuous current, and involve little or no risk of deranging the magnetism of the needles (294.).
309. iii. Chemical decomposition.--The chemical action of voltaic electricity is characteristic of that agent, but not more characteristic than are the laws under which the bodies evolved by decomposition arrange themselves at the poles. Dr. Wollaston showed[A] that common electricity resembled it in these effects, and "that they are both essentially the same"; but he mingled with his proofs an experiment having a resemblance, and nothing more, to a case of voltaic decomposition, which however he himself partly distinguished; and this has been more frequently referred to by some, on the one hand, to prove the occurrence of electro-chemical decomposition, like that of the pile, and by others to throw doubt upon the whole paper, than the more numerous and decisive experiments which he has detailed.
[A] Philosophical Transactions, 1801, pp. 427, 434.
310. I take the liberty of describing briefly my results, and of thus adding my testimony to that of Dr. Wollaston on the identity of voltaic and common electricity as to chemical action, not only that I may facilitate the repetition of the experiments, but also lead to some new consequences respecting electrochemical decomposition (376. 377.).
311. I first repeated Wollaston's fourth experiment[A], in which the ends of coated silver wires are immersed in a drop of sulphate of copper. By passing the electricity of the machine through such an arrangement, that end in the drop which received the electricity became coated with metallic copper. One hundred turns of the machine produced an evident effect; two hundred turns a very sensible one. The decomposing action was however very feeble. Very little copper was precipitated, and no sensible trace of silver from the other pole appeared in the solution.
[A] Philosophical Transactions, 1801, p. 429.
312. A much more convenient and effectual arrangement for chemical decompositions by common electricity, is the following. Upon a glass plate, fig. 43, placed over, but raised above a piece of white paper, so that shadows may not interfere, put two pieces of tinfoil a, b; connect one of these by an insulated wire c, or wire and string (301.) with the machine, and the other g, with the discharging train (292.) or the negative conductor; provide two pieces of fine platina wire, bent as in fig. 44, so that the part d, f shall be nearly upright, whilst the whole is resting on the three bearing points p, e, f place these as in fig. 43; the points p, n then become the decomposing poles. In this way surfaces of contact, as minute as possible, can be obtained at pleasure, and the connexion can be broken or renewed in a moment, and the substances acted upon examined with the utmost facility.
313. A coarse line was made on the glass with solution of sulphate of copper, and the terminations p and n put into it; the foil a was connected with the positive conductor of the machine by wire and wet string, so that no sparks passed: twenty turns of the machine caused the precipitation of so much copper on the end n, that it looked like copper wire; no apparent change took place at p.
314. A mixture of equal parts of muriatic acid and water was rendered deep blue by sulphate of indigo, and a large drop put on the glass, fig. 43, so that p and n were immersed at opposite sides: a single turn of the machine showed bleaching effects round p, from evolved chlorine. After twenty revolutions no effect of the kind was visible at n, but so much chlorine had been set free at p, that when the drop was stirred the whole became colourless.
315. A drop of solution of iodide of potassium mingled with starch was put into the same position at p and n; on turning the machine, iodine was evolved at p, but not at n.
316. A still further improvement in this form of apparatus consists in wetting a piece of filtering paper in the solution to be experimented on, and placing that under the points p and n, on the glass: the paper retains the substance evolved at the point of evolution, by its whiteness renders any change of colour visible, and allows of the point of contact between it and the decomposing wires being contracted to the utmost degree. A piece of paper moistened in the solution of iodide of potassium and starch, or of the iodide alone, with certain precautions (322.), is a most admirable test of electro-chemical action; and when thus placed and acted upon by the electric current, will show iodine evolved at p by only half a turn of the machine. With these adjustments and the use of iodide of potassium on paper, chemical action is sometimes a more delicate test of electrical currents than the galvanometer (273.). Such cases occur when the bodies traversed by the current are bad conductors, or when the quantity of electricity evolved or transmitted in a given time is very small.
317. A piece of litmus paper moistened in solution of common salt or sulphate of soda, was quickly reddened at p. A similar piece moistened in muriatic acid was very soon bleached at p. No effects of a similar kind took place at n.
318. A piece of turmeric paper moistened in solution of sulphate of soda was reddened at n by two or three turns of the machine, and in twenty or thirty turns plenty of alkali was there evolved. On turning the paper round, so that the spot came under p, and then working the machine, the alkali soon disappeared, the place became yellow, and a brown alkaline spot appeared in the new part under n.
319. On combining a piece of litmus with a piece of turmeric paper, wetting both with solution of sulphate of soda, and putting the paper on the glass, so that p was on the litmus and n on the turmeric, a very few turns of the machine sufficed to show the evolution of acid at the former and alkali at the latter, exactly in the manner effected by a volta-electric current.
320. All these decompositions took place equally well, whether the electricity passed from the machine to the foil a, through water, or through wire only; by contact with the conductor, or by sparks there; provided the sparks were not so large as to cause the electricity to pass in sparks from p to n, or towards n; and I have seen no reason to believe that in cases of true electro-chemical decomposition by the machine, the electricity passed in sparks from the conductor, or at any part of the current, is able to do more, because of its tension, than that which is made to pass merely as a regular current.
321. Finally, the experiment was extended into the following form, supplying in this case the tidiest analogy between common and voltaic electricity. Three compound pieces of litmus and turmeric paper (319.) were moistened in solution of sulphate of soda, and arranged on a plate of glass with platina wires, as in fig. 45. The wire m was connected with the prime conductor of the machine, the wire t with the discharging train, and the wires r and s entered into the course of the electrical current by means of the pieces of moistened paper; they were so bent as to rest each on three points, n, r, p; n, s, p, the points r and s being supported by the glass, and the others by the papers; the three terminations p, p, p rested on the litmus, and the other three n, n, n on the turmeric paper. On working the machine for a short time only, acid was evolved at all the poles or terminations p, p, p, by which the electricity entered the solution, and alkali at the other poles n, n, n, by which the electricity left the solution.
322. In all experiments of electro-chemical decomposition by the common machine and moistened papers (316.), it is necessary to be aware of and to avoid the following important source of error. If a spark passes over moistened litmus and turmeric paper, the litmus paper (provided it be delicate and not too alkaline,) is reddened by it; and if several sparks are passed, it becomes powerfully reddened. If the electricity pass a little way from the wire over the surface of the moistened paper, before it finds mass and moisture enough to conduct it, then the reddening extends as far as the ramifications. If similar ramifications occur at the termination n, on the turmeric paper, they prevent the occurrence of the red spot due to the alkali, which would otherwise collect there: sparks or ramifications from the points n will also redden litmus paper. If paper moistened by a solution of iodide of potassium (which is an admirably delicate test of electro-chemical action,) be exposed to the sparks or ramifications, or even a feeble stream of electricity through the air from either the point p or n, iodine will be immediately evolved.
323. These effects must not be confounded with those due to the true electro-chemical powers of common electricity, and must be carefully avoided when the latter are to be observed. No sparks should be passed, therefore, in any part of the current, nor any increase of intensity allowed, by which the electricity may be induced to pass between the platina wires and the moistened papers, otherwise than by conduction; for if it burst through the air, the effect referred to above (322.) ensues.
324. The effect itself is due to the formation of nitric acid by the combination of the oxygen and nitrogen of the air, and is, in fact, only a delicate repetition of Cavendish's beautiful experiment. The acid so formed, though small in quantity, is in a high state of concentration as to water, and produces the consequent effects of reddening the litmus paper; or preventing the exhibition of alkali on the turmeric paper; or, by acting on the iodide of potassium, evolving iodine.
325. By moistening a very small slip of litmus paper in solution of caustic potassa, and then passing the electric spark over its length in the air, I gradually neutralized the alkali, and ultimately rendered the paper red; on drying it, I found that nitrate of potassa had resulted from the operation, and that the paper had become touch-paper.
326. Either litmus paper or white paper, moistened in a strong solution of iodide of potassium, offers therefore a very simple, beautiful, and ready means of illustrating Cavendish's experiment of the formation of nitric acid from the atmosphere.
327. I have already had occasion to refer to an experiment (265. 309.) made by Dr. Wollaston, which is insisted upon too much, both by those who oppose and those who agree with the accuracy of his views respecting the identity of voltaic and ordinary electricity. By covering fine wires with glass or other insulating substances, and then removing only so much matter as to expose the point, or a section of the wires, and by passing electricity through two such wires, the guarded points of which were immersed in water, Wollaston found that the water could be decomposed even by the current from the machine, without sparks, and that two streams of gas arose from the points, exactly resembling, in appearance, those produced by voltaic electricity, and, like the latter, giving a mixture of oxygen and hydrogen gases. But Dr. Wollaston himself points out that the effect is different from that of the voltaic pile, inasmuch as both oxygen and hydrogen are evolved from each pole; he calls it "a very close imitation of the galvanic phenomena," but adds that "in fact the resemblance is not complete," and does not trust to it to establish the principles correctly laid down in his paper.
328. This experiment is neither more nor less than a repetition, in a refined manner, of that made by Dr. Pearson in 1797[A], and previously by MM. Paets Van Troostwyk and Deiman in 1789 or earlier. That the experiment should never be quoted as proving true electro-chemical decomposition, is sufficiently evident from the circumstance, that the law which regulates the transference and final place of the evolved bodies (278. 309.) has no influence here. The water is decomposed at both poles independently of each other, and the oxygen and hydrogen evolved at the wires are the elements of the water existing the instant before in those places. That the poles, or rather points, have no mutual decomposing dependence, may be shown by substituting a wire, or the finger, for one of them, a change which does not at all interfere with the other, though it stops all action at the changed pole. This fact may be observed by turning the machine for some time; for though bubbles will rise from the point left unaltered, in quantity sufficient to cover entirely the wire used for the other communication, if they could be applied to it, yet not a single bubble will appear on that wire.
[A] Nicholson's Journal, 4to. vol. I. pp. 311, 299. 349.
329. When electro-chemical decomposition takes place, there is great reason to believe that the quantity of matter decomposed is not proportionate to the intensity, but to the quantity of electricity passed (320.). Of this I shall be able to offer some proofs in a future part of this paper (375. 377.). But in the experiment under consideration, this is not the case. If, with a constant pair of points, the electricity be passed from the machine in sparks, a certain proportion of gas is evolved; but if the sparks be rendered shorter, less gas is evolved; and if no sparks be passed, there is scarcely a sensible portion of gases set free. On substituting solution of sulphate of soda for water, scarcely a sensible quantity of gas could be procured even with powerful sparks, and nearly none with the mere current; yet the quantity of electricity in a given time was the same in all these cases.
330. I do not intend to deny that with such an apparatus common electricity can decompose water in a manner analogous to that of the voltaic pile; I believe at present that it can. But when what I consider the true effect only was obtained, the quantity of gas given off was so small that I could not ascertain whether it was, as it ought to be, oxygen at one wire and hydrogen at the other. Of the two streams one seemed more copious than the other, and on turning the apparatus round, still the same side in relation to the machine; gave the largest stream. On substituting solution of sulphate of soda for pure water (329.), these minute streams were still observed. But the quantities were so small, that on working the machine for half an hour I could not obtain at either pole a bubble of gas larger than a small grain of sand. If the conclusion which I have drawn (377.) relating to the amount of chemical action be correct, this ought to be the case.
· · ·
End of part 6 of 31
Continue readingSeries III: Identity of Electricities Derived from Different Sources (Part 2)
Starvard